\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=2\cdot0,15=0,3\left(mol\right)\)

Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên sau p/ứ Zn dư

\(\Rightarrow n_{Zn}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\\ \Rightarrow m_{Zn}=0,15\cdot65=9,75\\ \Rightarrow m_{Zn\left(dư\right)}=13-9,75=3,25\left(g\right)\\ c,n_{H_2}=n_{Zn}=0,15\left(mol\right)\\ \Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)

\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)

a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)

n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)

PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)

            0,2     0,5

Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)

n\(Zn\) hết , n\(HCl\) dư

-->Tính theo số mol hết

               Zn + 2HCl->ZnCl\(2\) + H\(2\)

              0,2 ->  0,4      0,2        0,2

n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)

m​\(HCl\) dư= 0,1.36,5 = 3,65(g)

b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)

c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)

d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)

 3H2 +Fe2O3 → 2Fe + 3H2O

  0,2       0,12

Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)

    nH2 hết .Tính theo số mol hết

\(HCl\)

​ 3H2 +Fe2O3 → 2Fe + 3H2O

0,2->                  0,2

m\(Fe\)=n.M= 0,2.56= 11,2(g)

Câu 1 :

a)  PTHH : 

 \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\) (1) 

  \(H_2+CuO\underrightarrow{t^o}Cu+H_2O\)(2)

b) Ta có : \(n_{Zn}=\frac{3,5}{65}\approx0,054\left(mol\right)\)

Theo phương trình hóa học (1) :

\(n_{H_2}=n_{Zn}\approx0,054\left(mol\right)\)

\(\Rightarrow V_{H_2}\approx0,054\cdot22,4=1,2096\left(l\right)\)

c) Theo phương trình hóa học (2), ta có:

\(n_{Cu}=n_{H_2}\approx0,054\left(mol\right)\)

\(\Rightarrow m_{Cu}\approx0,054\cdot64=3,456\left(g\right)\)

Bài 2:

a) Ta có : \(n_{Al}=\frac{2,7}{27}=0,1\left(mol\right)\); \(n_{HCl}=\frac{200\cdot7,3}{100\cdot36,5}=0,4\left(mol\right)\)

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Theo phương trình hóa học : \(n_{H_2}=\frac{3}{2}n_{Al}=\frac{3}{2}.0,1=0,15\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)

b) Theo phương trình hóa học , ta có : \(n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\)

\(\Rightarrow m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\)

Lại có: \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)

Áp dụng định luật bảo toàn khối lượng, ta có:

\(m_{Al}+m_{dd_{HCl}}=m_{dd_{AlCl_3}}+m_{H_2}\)

\(\Leftrightarrow2,7+200=m_{dd_{AlCl_3}}+0,3\)

\(\Leftrightarrow m_{dd_{AlCl_3}}=202,4\left(g\right)\)

Vậy \(C\%_{dd_{AlCl_3}}=\frac{13,35}{202,4}\cdot100\%\approx6,6\%\)

\(a)n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=0,1mol\\ m_{Zn}=0,1.65=6,5g\\ m_{Cu}=9,7-6,5=3,2g\\ b)C_{\%ZnCl_2}=\dfrac{0,1.136}{6,5+120-0,1.2}\cdot100=10,77\%\)

\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)

\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(1........2\)

\(0.1......0.4\)

\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)

\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)

\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)

\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)

\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)

1)

a) Fe + 2HCl --> FeCl₂ + H₂

b) \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

           0,15->0,3--->0,15-->0,15

=> V_H2 = 0,15.22,4 = 3,36 (l)

c) m_{dd sau pư} = 8,4 + 250 - 0,15.2 = 258,1 (g)

=> \(C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%=7,38\%\)

2)

a) Zn + 2HCl --> ZnCl₂ + H₂

b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            0,2-->0,4---->0,2--->0,2

=> V_H2 = 0,2.22,4 = 4,48 (l)

m_ZnCl2 = 0,2.136 = 27,2 (g)

c) \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,2}=2M\)

d) 

PTHH: A + 2HCl --> ACl₂ + H₂

           0,2<--0,4

=> \(M_A=\dfrac{4,8}{0,2}=24\left(g/mol\right)\)

=> A là Mg(Magie)

\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

0,2                      0,2          0,3 

\(V_{H_2}=n.22,4=6,72\left(l\right)\)

\(m_{AlCl_3}=n.M=0,2.133,5=26,7\left(g\right)\)

a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b) \(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\) ;    \(n_{HCl}=\dfrac{m}{M}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

 \(2Al\)    \(+\)   \(6HCl\)    →    \(2AlCl_3\)  \(+\)  \(3H_2\)

Tỉ lệ:   \(\dfrac{0,2}{2}>\dfrac{0,5}{6}\)                                          ⇒  Al dư, tính theo HCl

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

           \(0,5\)    →   \(\dfrac{1}{6}\)    →   \(0,25\)       ( mol )

\(V_{H_2}=n.22,4=0,25.22,4=5,6\left(l\right)\)

c) \(m_{AlCl_3}=n.M=\dfrac{1}{6}.\left(27+35,5.3\right)=22,25\left(g\right)\)

a)

$2Al +3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
b)

$n_{H_2} = n_{H_2SO_4} = \dfrac{300.9,8\%}{98} = 0,3(mol)$
$V_{H_2} = 0,3.22,4 = 6,72(lít)$

c)

$n_{Al_2(SO_4)_3} = \dfrac{1}{3}n_{H_2SO_4} = 0,1(mol)$
$m_{Al_2(SO_4)_3} = 0,1.342 = 34,2(gam)$

d)

$n_{Al} = \dfrac{2}{3}n_{H_2SO_4} = 0,2(mol)$
$m_{dd} = 0,2.27 + 300 - 0,3.2 = 304,8(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{34,2}{304,8}.100\% = 11,22\%$

nH2SO4=0,3(mol)

PTHH: 2Al + 3 H2SO4 -> Al2(SO4)3 + 3 H2

a) 0,2_______0,3______0,1______0,3(mol)

b) V(H2,đktc)=0,3.22,4=6,72(l)

c) a=mAl=0,2.27=5,4(g)

=>a=5,4(g)

d)  mAl2(SO4)3=342.0,1=34,2(g)

e) mddAl2(SO4)3= 5,4+ 300 - 0,3.2= 304,8(g)

=>C%ddAl2(SO4)3= (34,2/304,8).100=11,22%

a) Phương trình hóa học:

              2Al+ 3H₂SO₄→ Al₂(SO₄)₃+ 3H₂

( mol)      0,2       0,3            0,1          0,3                                        

b) m H₂SO₄= \(\dfrac{9,8\%.300}{100\%}=29,4\)(gam)

→n H₂SO₄= \(\dfrac{m}{M}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

=> m_Al= \(n.m=0,2.27=5,4\left(gam\right)\)

c) V H₂= n.22,4= 0,3.22,4= 6,72( lít)

m H₂= n.M= 0,3.2= 0,6(gam)

d) m Al₂(SO₄)₃= n.M= 0,1.342= 34,2(gam)

e) m_{dd sau phản ứng}= m_Al+ m_ddH₂SO₄- m H₂

                                    = 5,4  + 300- 0,6= 304,8(gam)

=> C%_{dd sau phản ứng}=\(\dfrac{34,2}{304,8}.100\%=11,22\%\)